With one hand reaching toward the sky, Rihanna looked smoking hot on the cover of her new single, "Russian Roulette," which debuted Oct. 20. She showed off a slicked-back Mohawk, eye patch, and went topless. The song is the first single to be released from her upcoming LP, "Rated R," which will hit stores Nov. 23 from Def Jam. A press release from Def Jam said Rihanna worked with Tricky Stewart, Justin Timberlake, Chase & Status, and Stargate on the album. Ne-Yo wrote and produced "Russian Roulette." The album is Rihanna's first release since 2007's hit-spawning "Good Girl Gone Bad," which was re-released this January. (PRNewsFoto/Island Def Jam Music Group/AP Photo )